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Research (13)

Laser Raman Miscoscopy for fibre stress measurements at the microscale

fig research 33Laser Raman Microscopy (LRM) is the only experimental technique able to measure stress or strain on individual fibres at the microscopic level. The Raman wavenumbers of certain vibrational modes of crystalline materials – such as carbon, SiC or Kevlar fibres embedded in composites – are stress/strain dependent, most frequently through a simple linear relation that can be established experimentally and constitutes the fibre-specific Raman Calibration Curve (RCC). The RCC of a fibre can be used reversely to translate shifts captured from the same type of fibre in a composite material, to stress/strain.

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Fracture behaviour and mechanical properties of composites

Understanding the fracture behavior of composite materials is a key parameter in optimizing design  and production routes as well as their mechanical performance. We study the mechanical and fracture behaviour of polymer- and ceramic-matrix composite materials under a wide range of specimen geometries and loading configurations. We are interested in identifying the damage and failure mechanisms developing at the microscale during loading as well as in understanding their correlation and evaluating their role in the material failure.

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Autoclave processing of polymer- and epoxy- matrix composites

Our semi-industrial autoclave by Aeroform Limited (Poole, UK) can run simultaneous temperature/pressure/vacuum profiles within the ranges of 25 to 225°C and -1 to 10 Bar. We use the chamber to cure mainly polymer- and epoxy-matrix composites, custom laminates (eg with embedded SMA actuators) and nanocomposite materials (eg buckypapers). The autoclave's pressurized environment is also used in investigating watertightness of submersed structures. Manufacturing possibilities include Resin Film Infusion (RFI), Vacuum Bagging, Resin Transfer Infusion (RTI), Prepreg, and Wet/Hand-layup.

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Development and testing of self-deformed composites

fig research 24bA multifunctional composite without insertion of actuators can be developed by exploiting the thermal anisotropy of a composite laminate in order to induce shape changes by internal heating. Indeed a selective thermal activation of one or more layers inside the material would create thermal stresses, which could induce shape change to the material at the macroscopic level, just as those observed in the bimetallic strips.

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Ferromagnetic SMA and related composites

fig research 23aModern technologies need transducing materials, which combine large strains, high-force production and fast dynamic response during an actuation event. The functionality of these materials is based on the physical mechanisms responsible for the electric, magnetic or thermal energy transformations into mechanical work, which produce the actuation. The reverse energy conversion is in use for sensing. The efficiency, power density and speed of these types of energy conversion determine the advantages and drawbacks of these materials in the applications.

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Shape Memory Alloy (SMA) wires as activators in polymers & composites

fig research 21aThe integration of pre-strained Shape Memory Alloy wires with small diameters in fibre reinforced polymer composites leads from the engineering structural materials to the so-called adaptive or smart composite materials.

Adaptive materials integrate actuating and sensing components, which are very often totally different materials, into a structural one. These materials or material systems can vary some of their properties and/or functions, such as stiffness, damping capacity or even shape, in response to an external or internal stimulus. It is obvious that not only their overall mechanical performance, but also their adaptive functions are significantly affected by the quality of the interfacial regions between their constituents.

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Synthesis and mechanical properties of supramolecular composites

fig research 16aBlock copolymers are excellent candidates for a bioinspired “bottom-up” strategy to design and develop composite materials with superior multifunctional properties. This is due to the scale of the microdomains (nanometers) where improved physical and mechanical properties (hydrophilic, hydrophobic, stiffness ductility) are met within the same supramolecular structure. Moreover, block copolymers can be tuned to the size and shape of self-assembled morphologies for which there are no interfacial and/or phase separation problems.

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Preparation and Characterisation of Graphene films and tapes

fig research 15aFree-standing paper-like or foil-like materials based on modifications of elemental carbon draw a great attention over the last years. Their proposed or already implemented uses include protective layers, chemical filters, components of electrical batteries or supercapacitors, adhesive layers, electronic or optoelectronic components, and molecular storage. Similarly to buckypapers prepared from carbon nanotubes by vacuum filtration, a free-standing membrane can be made by a flow-directed assembly of individual graphene or graphene oxide sheets.This new material outperforms many other paper-like materials in stiffness and strength. Its combination of macroscopic flexibility and stiffness is a result of a unique interlocking-tile arrangement of the nanoscale sheets.

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Mechanical Properties of Graphene

fig research 14aGraphene is a two-dimensional crystal, consisting of hexagonally-arranged covalently bonded carbon atoms and is the template for one dimensional CNTs, three dimensional graphite, and also of important commercial products, such as polycrystalline carbon fibres (CF). As a single, virtually defect-free crystal, graphene is predicted to have an intrinsic tensile strength higher than any other known materials and tensile stiffness similar to graphite. In graphitic materials, such as CF, the variation of phonon frequency per unit of strain can provide information on the efficiency of stress transfer to individual bonds. Indeed, the higher the crystallinity of a fibre (and hence the modulus) the higher the degree of bond deformation and, hence, the higher the measured Raman shift per unit strain.

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Preparation of CNT/ Epoxy Nanocomposites

fig research 13bThe classic methods for low volume fraction polymer nanocomposites based on CNTs involve melt blending, solution casting, solution mixing, direct mixing and in-situ polymerization. However, using these techniques has resulted in phase separation between polymer and CNTs, low polymer wetting of CNTs and low interfacial shear strength between polymer matrix and CNTs.

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